BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids† †Electronic supplementary information (ESI) available: Details on the synthesis and purification of BODIPY dyes and ILs, sample preparations and physical properties of ILs as well as spectral data. See DOI: 10.1039/c4ra09757b Click here for additional data file.
نویسندگان
چکیده
1 SUPPORTING INFORMATION BODIPY-BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids Joseph D. Kimball, Sangram Raut, Laramie P. Jameson, Nicholas W. Smith, Zygmunt Gryczynski* and Sergei V. Dzyuba a Department of Physics and Astronomy, Texas Christian University, Fort Worth, TX 76129, USA. Fax: +1 817 257 7742; Tel: +1 817 257 4209; E-mail: [email protected] b Department of Chemistry, Texas Christian University, Fort Worth, TX 76129, USA. Fax: +1 817 257 5851; Tel: +1 817 257 6218; E-mail: [email protected]
منابع مشابه
An unprecedented amplification of near-infrared emission in a Bodipy derived π-system by stress or gelation† †Electronic supplementary information (ESI) available: Experimental details, synthesis procedures and characterization data of the compounds, and additional figures. CCDC 1523313. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01696d Click here for additional data file. Click here for additional data file.
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A dual-response BODIPY-based fluorescent probe for the discrimination of glutathione from cystein and homocystein† †Electronic supplementary information (ESI) available: Synthesis, spectroscopic properties, NMR and mass spectra. See DOI: 10.1039/c5sc00216h Click here for additional data file.
1. Time dependent spectral changes of BODIPY-S in the presence of thiols. ......S2 2. MS of BODIPY-S with GSH, Cys and Hcy..............................................S3 3. Photophysical spectra of BODIPY 4 and BODIPY-S +Cys..........................S4 4. Time dependent Spectral changes of S-S-BODIPY in the presence of thiols. ...S5 5. NMR and MS of the product of S-S-BODIPY with thiols..........
متن کاملBODIPY-BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids.
A symmetrical BODIPY-BODIPY dyad with a diyne linker was prepared in two steps; the lifetime decay of this rotor appeared to correlate with the viscosity of the media, thus making this dyad a suitable small molecule viscometer for molecular solvents. The potential of using the rotor to probe the viscosity of ionic liquids was also investigated.
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Total synthesis of malagashanine: a chloroquine potentiating indole alkaloid with unusual stereochemistry† †Electronic supplementary information (ESI) available: Experimental details and spectral data are provided. CCDC 1489617. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03578g Click here for additional data file. Click here for additional data file.
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