BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids† †Electronic supplementary information (ESI) available: Details on the synthesis and purification of BODIPY dyes and ILs, sample preparations and physical properties of ILs as well as spectral data. See DOI: 10.1039/c4ra09757b Click here for additional data file.

نویسندگان

  • Joseph D. Kimball
  • Sangram Raut
  • Laramie P. Jameson
  • Nicholas W. Smith
  • Zygmunt Gryczynski
  • Sergei V. Dzyuba
چکیده

1 SUPPORTING INFORMATION BODIPY-BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids Joseph D. Kimball, Sangram Raut, Laramie P. Jameson, Nicholas W. Smith, Zygmunt Gryczynski* and Sergei V. Dzyuba a Department of Physics and Astronomy, Texas Christian University, Fort Worth, TX 76129, USA. Fax: +1 817 257 7742; Tel: +1 817 257 4209; E-mail: [email protected] b Department of Chemistry, Texas Christian University, Fort Worth, TX 76129, USA. Fax: +1 817 257 5851; Tel: +1 817 257 6218; E-mail: [email protected]

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منابع مشابه

A dual-response BODIPY-based fluorescent probe for the discrimination of glutathione from cystein and homocystein† †Electronic supplementary information (ESI) available: Synthesis, spectroscopic properties, NMR and mass spectra. See DOI: 10.1039/c5sc00216h Click here for additional data file.

1. Time dependent spectral changes of BODIPY-S in the presence of thiols. ......S2 2. MS of BODIPY-S with GSH, Cys and Hcy..............................................S3 3. Photophysical spectra of BODIPY 4 and BODIPY-S +Cys..........................S4 4. Time dependent Spectral changes of S-S-BODIPY in the presence of thiols. ...S5 5. NMR and MS of the product of S-S-BODIPY with thiols..........

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BODIPY-BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids.

A symmetrical BODIPY-BODIPY dyad with a diyne linker was prepared in two steps; the lifetime decay of this rotor appeared to correlate with the viscosity of the media, thus making this dyad a suitable small molecule viscometer for molecular solvents. The potential of using the rotor to probe the viscosity of ionic liquids was also investigated.

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عنوان ژورنال:

دوره 5  شماره 

صفحات  -

تاریخ انتشار 2015